[8+2] Cycloadditions of Vinylphenylfurans and DMAD:a Combined Experimental and DFT Studies

• 作 者: KaiChen[1]FengWu[1]LijuanYe[1]ZiyouTian[2]Zhi-XiangYu[2]ShifaZhu[1]
• 机 构: School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou,510640
• 出 处: 中国化学会第30届学术年会
• 发表日期: 2016年期

　　The [8+2]-cycloaddition reaction can provide a straight-forward approach for the synthesis of 10-membered ring compounds.In this study,a formal [8+2] cycloaddition reaction of vinylphenylfuran and DMAD in three different systems,forming a variety of polycyclic compounds,have been reported.Both experimental and computational studies were applied to understand the potential reaction mechanism.