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The recent advent of porous coordination polymers (PCPs) or metal-organic frameworks (MOFs) as new functional microporous materials,have attracted the attention of chemists and physicists due to not only scientific but also application interest in the creation of unprecedented regular nano-sized spaces and in the finding of novel phenomena[1-3].Our target is for solid state ion conductors,which are utilized in various devices such as batteries and fuel cells[4].Recently,PCPs (and CPs) have been emerging as a novel and fascinating platform for solid ion conductors especially in the field of solid proton conductors.We could develop several approaches to acquire unique ion conductive property by designing modules of PCPs and guests[5].