钴基配位聚合物Co2(1,4-NDC)2(DMF)2的合成与结构研究

来源 :河南省化学会2016年学术年会 | 被引量 : 0次 | 上传用户:zyh_0527
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  1,4-萘二甲酸(1,4-NDCH2)配体具有多样的配位模式,利于实现结构的调控,已引起人们广泛的研究兴趣[1]。本文利用溶剂热法,以1,4-萘二甲酸和N,N-二甲基甲酰胺(DMF)作为有机配体合成了一例具有三维(3D)结构的配位聚合物:Co2(1,4-NDC)2(DMF)2(1)。
其他文献
Monofluoromethylation has attracted substantial attention in organic synthesis,owing to the increasing important application of selectively fluorinated organics in medicinal chemistry and materials sc
N-Fused heterocycles have attracted much interest since they are widely present in naturally occurring alkaloids and synthetic compounds with a broad spectrum of biological activities.
Natural products that target RNA include the macrolides(e.g.,erythromycin,clarythromycin,and azithromycin)and the aminoglycosides(e.g.,tobramycin and gentamicin).
汞是造成环境污染的主要重金属离子之一,在浓度很低时对生物体就表现出极强的生理毒性。且汞易经生物富集作用最终转移到人类体内,且无法通过自身代谢作用排出体外,严重危害人类的身体健康。因此,对生物体和环境中汞的分析检测一直是人们非常关注的问题,建立快速、高效的汞离子检测方法在生命科学、医学、环境保护等领域中具有重大意义。
会议
Recently,many reports show that the 6-arylpurine derivatives possess anti-HCV,cytostatic,and antimycobacterial activities.Up to now,several methodologies were described for the preparation of 6-arylpu
2-substituted purine nucleosides have received considerable attention due to their broad spectrum of biological activities.Thus,numerous economically important pharmaceuticals,such as cladribine,Regad
1,4-Dihydro-2H-3,1-benzoxazin-2-one is an important structural motif and is widely found in biologically active compounds.For example,efavirenz is a well-known nonnucleoside reverse transcriptase inhi
A transition metal free oxidative dehydrogenative coupling reaction has been developed for the direct construction of novel C60-fused tetrahydrocarbazoles,dibenzothiophenes,benzothiophenes and dibenzo
An efficient redox neutral N-heteroannulation reaction has been developed to selective access unexpected unsymmetrical fulleropyrrolidines and diverse disubstituted 1-fulleropyrrolines using a very si
A facile and direct synthetic method for the synthesis of vicinal tricarbonyl amides(VTAs)in moderate to excellent yields(62-93%)has been developed starting from readily available β-ketoamide in the p