Manganese(Ⅲ)-mediated Phosphinoyl Radical Reactions for Selective Synthesis of Phosphinoylated 3,4-D

来源 :The 24th International Society of Heterocyclic Chemistry Con | 被引量 : 0次 | 上传用户：yezilei311

【摘要】

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【作者】

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Da-Peng Li Xiang-Qiang Pan Jian-Ping Zou Wei Zhang

【机构】

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College of Chemistry and Chemical Engineering,Suzhou University,199 Renai Street,Suzhou,Jiangsu 2151

【出处】

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The 24th International Society of Heterocyclic Chemistry Con

【发表日期】

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2013年4期

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Phosphinoylated 3, 4-dihydronaphathalenes were synthesized by the reaction of phosphinoyl radical mediated by Mn(OAc)3 with 1,4-diarylbutynes.The reaction behave straitforward, good selectivity and yields under the mild conditions, it work through phosphinoyl radical addition-translocation-cyclization in one-pot.

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Manganese(Ⅲ)-mediated Phosphinoyl Radical Reactions for Selective Synthesis of Phosphinoylated 3,4-D

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