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In this study, AZ31B magnesium alloy was treated by different kinds of silanes, including γ-(2,3-epoxypropoxy) propyltrimethoxysilane (KH-560), γ-(methacryloxy) propyltrimethoxysilane (KH-570), N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (KH-792) and bis-1,2-(triethoxysilyl) ethane (BTSE), through the method of electro-deposition.