【摘 要】
：
We report here the synthesis of three new nickel(Ⅱ)complexes: [Ni(PzTA)2CO3]·5H2O(PzTA = 2,4-diamio-6-(2-pyrazin)-1,3,5-triazine)in 1,[NiQ(PyTA)(H2O)2]Cl·H2O(HQ = 8-hydroxyquinoline,PyTA = 2,4-diamino
【机 构】
：
College of Materials and Energy,South China Agricultural University,Guangzhou,510642
论文部分内容阅读
We report here the synthesis of three new nickel(Ⅱ)complexes: [Ni(PzTA)2CO3]·5H2O(PzTA = 2,4-diamio-6-(2-pyrazin)-1,3,5-triazine)in 1,[NiQ(PyTA)(H2O)2]Cl·H2O(HQ = 8-hydroxyquinoline,PyTA = 2,4-diamino-6-(2-pyridyl)-1,3,5-triazine)in 2,[NiQ(PzTA)(H2O)2]Cl·H2O in 3,and they were characterized by UV spectroscopy,elemental analysis,molar conductivity and X-ray single crystal diffraction(CCDC number of 2 and 3 are 996889 and 996892,respectively).
其他文献
金属有机骨架在离子交换、催化、吸附、发光及磁性领域具有潜在的应用[1],而簇-有机骨架的研究尚处于发展阶段.本文报道一个新颖的簇-有机骨架 [Yb3CuCl(μ3-OH)3(in)6(H2O)2]·2H2O,其结晶学参数为orthorhombic,space group P212121,a = 12.0021(1)(A),b = 18.2238(2)(A),c =20.7920(2)(A).
Truxene(10,15-dihydro-5H-diindeno[1,2-a;1′,2′-c]-fluorene),a C3h symmetric polycyclic hydrocarbon,has attracted a great deal of interest and intensively been considered as a promising building block t
The design and synthesis of polynuclear clusters have been fueled by their intriguing architectures and various potential applications [1-3].
多孔配位聚合物(Porous Coordination Polymer,PCP),亦称金属—有机框架(Metal-Organic Framework,MOF),近年来受到广泛关注。除了结构与性质多样化可设计调控等特点,多孔配位聚合物还具备明显的框架柔性行为,可以产生一些不同寻常的吸附性质。
The reactions of copper(Ⅰ)salts CuX [X = I,SCN,BF4,OTf(OTf = CF3SO3)and ClO4] and bis[2-(diphenylphosphino)phenyl]ether(pop)with 4,4-bipyridine(bipy),2,2-bipyridine(bpy),1,10-phenanthroline(Phen)and [
Trivalent lanthanide ions have always attracted great attention due to their sharp and intense f→f emissions covering UV to near-infrared(NIR)range with potential applications in light-emitting diodes
Five crystals of(1)[Eu2(TPTZ)2(mNBA)6(H2O)2]·CH3OH,(2)[Eu(TPTZ)(CF3COO)(H2O)5]·Cl2,(3){[Yb2(TPTZ)2(BDC)3]·H2O}n,(4)[Yb(TPTZ)Cl(H2O4)]·Cl2 and(5)[Er(TPTZ)(TTA)Cl2]Cl(mNBA = m-nitro benzoate,BDC = terep
A series of lanthanide(Ⅲ)metal-organic coordination polymers [Ln(L)(H2O)2]·Solvent {Ln =Pr(1),Sm(2),Eu(3),Gd(4),Tb(5),Dy(6),Ho(7)} {H3L=5-(6-carboxynaphthalen-2-yl)isophtahalic acid} have been synthes
Water oxidation plays a critical role in solar water splitting.[1] Herein we report the crystallographic characterization of a RuⅢ-O-RuⅣ-O-RuⅢ type trinuclear ruthenium intermediate to shed light on t
H2O2 detection has attracted much attention in recent years due to that its production may affect many biochemistry reactions in the body that may be dangerous for human health.