【摘 要】
：
The reactions of copper(Ⅰ)salts CuX [X = I,SCN,BF4,OTf(OTf = CF3SO3)and ClO4] and bis[2-(diphenylphosphino)phenyl]ether(pop)with 4,4-bipyridine(bipy),2,2-bipyridine(bpy),1,10-phenanthroline(Phen)and [
【机 构】
：
Department of Chemistry,Capital Normal University,Beijing 100048,China
论文部分内容阅读
The reactions of copper(Ⅰ)salts CuX [X = I,SCN,BF4,OTf(OTf = CF3SO3)and ClO4] and bis[2-(diphenylphosphino)phenyl]ether(pop)with 4,4-bipyridine(bipy),2,2-bipyridine(bpy),1,10-phenanthroline(Phen)and [2,3-f]-pyrazino-[1,10]phenanthroline-2,3-dicarbonitrile(C16H6N6)lead to seven copper(Ⅰ)complexes: {[Cu2(POP)2(4,4-bipy)](OTf)2·4CH3CN}n(1),{[Cu(POP)(bpy)](BF4)}n(2),{[Cu(POP)(phen)](ClO4)}·CH3OH·H2O(3),{[Cu(POP)(C16H6N6)I]}(4),[Cu(POP)(C16H6N6)](5),[Cu(xantphos)(bpy)]CLO4(6),[Cu(xantphos)(bpy)](CF3SO3)(7).
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