【摘 要】
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INTRODUCTION The Dakin and Baeyer-Villiger(BV)reactions are classic synthetic approaches in organic chemistry for the oxidation of carbonyl groups.They are are used extensively in various fields,parti
【机 构】
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Shenzhen Jianyin Wealth Investment Holdings Co.,Ltd.,Shenzhen,518055,China
【出 处】
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中国化学会第十二届全国微全分析系统学术会议、第七届全国微纳尺度生物分离分析学术会议、第七届国际微流控学学术论坛
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INTRODUCTION The Dakin and Baeyer-Villiger(BV)reactions are classic synthetic approaches in organic chemistry for the oxidation of carbonyl groups.They are are used extensively in various fields,particularly,in the synthesis of pharmaceuticals,agrochemicals,food additives,antioxidants,and the degradation of xenobiotic toxins.However,most of the modern synthetic strategies for these oxidation reactions require explosive and ha zardous peroxides,high concentrations of acid or base or expensive organometallic compounds as cataly sts.Despite recent progress,these oxidation reactions require further improvements with particular focus on a milder chemical synthetic route instead of using hazardous organic solvents,oxidants,and catalysts.
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