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Recently, intense interest has been focused on studies of cubane-like poly-nuclear complexes due to their relevance to multi-electron transfer centers systems, and to their interesting properties .Tetranuclear cubane-like Ni complexes have been extensively investigated since the pioneering work of Andrew and Blake . A number of cubane-like complexes involving bridging ome, or alkoxo have beenpreviously reported. To understand the active role the transition metal ion played in the process of organicsynthesis and interestine molecular nrooerties.