Nd(Ⅲ)-Cu(Ⅱ) 15-MC-5金属冠醚的合成、结构

来源 :2017年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户：hyzxp01

【摘要】

：

　　近年来，金属冠醚由于在生物活性、磁性等领域的广泛应用使其成为配位化学研究的热点.我们利用甘氨酸羟肟酸(H2glyha)为配体，通过与铜盐和稀土盐反应得到了一个3d-4f混合金

【作者】

：

张佳窦建民杨华李大成

【机构】

：

山东省化学储能与新型电池技术重点实验室,聊城大学化学化工学院,山东聊城,252059

【出处】

：

2017年中西部地区无机化学化工学术研讨会

【发表日期】

：

2017年期

【关键词】

：

金属冠醚合成生物活性混合金属化学研究单晶衍射稀土盐羟肟酸

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论文部分内容阅读

　　近年来，金属冠醚由于在生物活性、磁性等领域的广泛应用使其成为配位化学研究的热点.我们利用甘氨酸羟肟酸(H2glyha)为配体，通过与铜盐和稀土盐反应得到了一个3d-4f混合金属的金属冠醚{Nd(OAc)2[15-MCcuⅡN(glyha)-5](H2O)5}·NO3·3H2O(Fig.1)，并通过X-射线单晶衍射对其结构进行了表征.

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Nd(Ⅲ)-Cu(Ⅱ) 15-MC-5金属冠醚的合成、结构

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