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A novel macrocyclic zirconocene(Ⅳ)aromatic selenite [(CpZr)8L16]·2(Cp4Zr2(μ-O)Cl2)(complex 1)(Cp = cyclopentadienyl anion; L = 4-fluorobenzeneseleninic acid)was prepared by the reaction of bis(cyclopentadienyl)zirconium dichloride with 4-fluorobenzeneseleninic acid.