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In this work,α-NLT nanocomposites(NCs)and β-NLT NCs with diameter about~13 nm were fabricated by a high temperature decomposition reaction method.The effects of NLT structure on the enhanced red upconversion luminescence performance were investigated.Under 980 nm excitation from a diode laser,The β-NLT emitted dominant green UC emission while the α-NLT emitted dominant red UC emission.Furthermore,the possible ET mechanism was proposed on the basis of our experimental results.