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Few-layer molybdenum disulfide (MoS2) is attractive for applications in next-generation electronic and optoelectronic devices.For monolayer MoS2, it is established that both conduction band minimum (CBM) and valence band maximum (VBM) are at K point in Brillouin zone.For bilayer MoS2, it is known that VBM is at Γ point.However, whether K or Λ valley forms the CBM and how is the energy difference between them are still disputable.