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The co-assembly of block copolymers (BCP) with nanoscale inorganic objects through noncovalent interaction is an important way to fabricate polymer nanocomposites.However,how to improve the miscibility of inorganic/polymeric interface is an important scientific question, particularly for inorganic cluster polyoxometalate (POM)/BCP system.Until now, a general method to incorporate POM into BCP matrices is still lacking.