Supramolecular Chirality Transfer via the Entanglement of Alkyl Chains and Chiroptical Switch based

来源 :手性中国2014学术研讨会 | 被引量 : 0次 | 上传用户:houjhz
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The induction, transfer, amplification and memory of chirality are intriguing issues in exploring the origin of homochiral structures in Nature and for possible applications in the various fields such as enantioselective synthesis, sensing, drug delivery and molecular device applications.The process of chirality transfer can be realized either in a synthetic process or by virtue of a supramolecular chemistry approach.In the supramolecular approach, the chirality transfer can be realized from a chiral matrix or template to achiral molecules through various noncovalent interactions such as π-π stacking, hydrogen bonding, electrostatic and hydrophobic interactions.These noncovalent interactions should be appropriate to preserve the initial chiral matrix and to induce the chiral information transfer.
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