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A novel cobalt-free and noble metal-free nanowires composite material Pr0.6Sr0.4FeO3-δ-Ce0.9Pr0.1O2-δ(PSFOCPO)has been successfully developed via the electrospinning method.A fast-firing method is introduced to improve the contact between the composite cathode and the SSZ(10%Sc2O3-stabilized ZrO2)electrolyte,as well as to retain the original nanowires structure.The phase structure and morphology of the material have been characterized by means of X-ray powder diffraction(XRD)and scanning electron microscopy(SEM).