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Low molecular-mass organic gelators(LMOGs)have generated considerable interest during the past decade for the design of smart materials.In recent years,self-assembly of TTF derivatives through intermolecular interaction leads to gelation of some organic solvents and have been widely investigated for organic conducting materials.[1,2] Herein,we report a series of poly(aryl ether)dendron with an electroactive MPTTFs unit linked through an acyl hydrazone linkage as organogelators.