The cis-syn cyclobutane pyrimidine dimer(CPD)is the major photoproduct in the UV-induced DNA lesions.An electron injection into the dimer leads to the split
In recent years,a concept of so-called "frustrated Lewis pairs"(FLPs)have undergone remarkable development,especially in hydrogen(H2)and CO2 activation.[1][
Homogeneous gold catalysis become more and more attractive in modern organometallic chemistry.Rearrangement of propargylic esters by Au(Ⅰ)-complexes is a s
Amphiphiles self-assembly is an essential bottom-up approach of fabricating advanced functional materials.Self-assembled materials with desired structures a
Hydrogen energy,as a cleanly renewable source,has great potential to meet global energy and environmental requirements.Our group present general hydrogen ac
In 2016,Wang and co-authors reported the catalytic α-fluoroallenoate synthesis via N-heterocyclic carbene-catalyzed fluorination reaction of alkynals[1].
First-principles quantum mechanical/molecular mechanical(QM/MM)-free energy calculations1-4 have been performed to uncover how uricase catalyzes metabolic r
A number of transition-metal complexes have been found to be efficient catalysts for kinds of hydroboration.[1] This short paper presents a DFT study to mec