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Volatile organic compounds such as trichloroethene(TCE)and tetrachloroethene(PCE)cause the contamination of groundwater and soil pollution.We have showed in the previous study that TCE was decomposed by the photoreaction of complexes such as ferric oxalate,ferric citrate ferric tartrate.In this study,we have investigated photodegradation of TCE utilizing iron ion and organic acid included in waste.