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Synthesizing and controlling plasmonic nanostructures such as Au and Ag nanoparticles (AuNPs and AgNPs) with high precision and high yield are of paramount importance in optics, nanoscience and materials science.It is particularly important to generate and control ~l-rim plasmonic gap because plasmonic gaps of~1 nm or less can generate exponentially stronger plasmonic coupling signals than >1-nm plasmonic gap.