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With the hydro/solvothermal reactions of 5-substituted tetrazolyl derivatives (HL) with Zn(Ⅱ) salts in the presence of the auxiliary ligand 4-pyridinecarboxylic acid (HPyc),two novel Zn(II) metal-organic frameworks formulated as {[ZnL(pyc)]·[(CH3)2NH]}n (1),{[ZnL2]·4H2O}n (2) have been synthesized.