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The electrokinetic conductivity (streaming or electrical) of nanochannels is a widely used technique for several nanofluidic applications which is known to be strongly dependent on solution properties (e.g.pH and ionic strength) and surface charge of the solid-liquid interface.In order to calculate the local surface charge, a modified electrical triple layer model (METLM) is developed for the first time which coupled with Poisson-Nemst-Planck+Navier-Stokes equations.