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  5. Surface-confined supramolecular coordination in a nano-reactor: STM reveals

Surface-confined supramolecular coordination in a nano-reactor: STM reveals

来源 :International Conference on Nanoscience & Technology,China 2 | 被引量 : 0次 | 上传用户：heyzol
【摘 要】
：
Utilizing the rectangular network formed by 1,3,5-tris(10-carboxydecyloxy) benzene (TCDB) as a nano-reactor, the supramolecular coordination of zinc (Ⅱ) phthalocyanine (Zn-Pc) with 4, 4-di (pyridine)-
【作 者】
：
Xuemei Zhang Qingdao Zeng Chen Wang 
【机 构】
：
National Center for Nanoscience and Technology,China,Beijing 100190,China
【出 处】
：
International Conference on Nanoscience & Technology,China 2
【发表日期】
：
2013年3期
【关键词】
：
STM nano-reactor coordination phthalocyanine bi-pyridine 
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　　Utilizing the rectangular network formed by 1,3,5-tris(10-carboxydecyloxy) benzene (TCDB) as a nano-reactor, the supramolecular coordination of zinc (Ⅱ) phthalocyanine (Zn-Pc) with 4, 4-di (pyridine)-ethene (DPE) has been performed at the 1-phenyloctane/HOPG interface.The coordination process is probed by scanning tunneling microscopy (STM) technique.Based on the submolecular resolved STM images, we can deduce that one DPE molecule coordinates two Zn-Pc molecules to form a novel H-shaped supramolecular complex.
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