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Two isostructural microporous flexible lanthanide metal-organic frameworks (FL-MOFs) formulated as [Ln (TTTPC)(NO2)2(Cl)]·(H2O)10 {Ln =Ce (1) and Tb (2) H3TTTPC =1,1,1"-tris(2,4,6-trimethylbenzene-1,3,5-triyl)-tris(methylene)-tris(pyridine-4-carboxylic acid);has been synthesized in large scale under microwave-assisted (MW) solvothermal reaction for 5 min.