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As an emerging branch of carbon-based nanomaterials,carbon nanodots(CDs)are inspiring intensive research efforts for their attractive merits.[1,2]Construction of Supra-CDs by self-assembling CDs is a new way to endow novel properties.Herein,water triggered luminescent carbon "nano-bombs" are developed based on supra-CDs,which is partially alkyl-chain-functionalized carbon dots agglomerates.