【摘 要】
:
tung oil is an important strategic materials and reproducible biomass resources.However,the major application is still in the field of traditionally thermal cur
【机 构】
:
CollegeofMaterialsandEnergy,SouthChinaAgriculturalUniversity,Guangzhou510642
【出 处】
:
第五届岭南有机化学论坛暨华南理工大学-兰州大学有机化学双边论坛
论文部分内容阅读
tung oil is an important strategic materials and reproducible biomass resources.However,the major application is still in the field of traditionally thermal curing paint and coating with lower additional value.Therefore,it is of practical significance and scientific value to modify the structures of tung oil and investigate the novel curing system.So,in this paper,eleostearic acid glyceride,as the main component of tung oil,was transformed to methyl eleostearate by transesterification,and then catechol or derivatives was introduced by Friedel-Crafts alkylation,along with the catalytic effect of acidic ionic liquid on the reaction was studied.According to this study,tung oil can be modified by alkylation to obtain high reactivity and excellent anti-corrosion derivatives,moreover it is also very important for expanding the application of tung oil and nature oil by constructing their new UV curing system.(Scheme 1).
其他文献
Spiroacetals have widely emerged in a myriad of biologically active natural products of different origins including plants,fungi,and marine organisms.The spiroa
Imidazo[1,2-a]pyridines are important skeletons for various useful molecules that exhibit a wide variety of biological activities,and they are also versatile bu
Transition-metal-catalyzed carbon-carbon cleavage offers unique opportunities to develop novel transformations,because it allows reorganization of bond connecti
A novel ruthenium-catalyzed dehydrogenative β-alkylation of 1,2,3,4-tetrahydroquinolines with aldehydes has been demonstrated,1 which enables assembling a wide
Through a ruthenium-catalyzed selective hydrogen transfer coupling reaction,a novel straightforward synthesis of 1,2,3,4-tetrahydronaphthyridines(THNADs) from o
Recent studies have revealed that heterocycles containing P-substituents show unique bioactivities and chemical properties,which lead them to a broad applicatio
Pyrrole skeleton represents an interesting class of nitrogen-containing heterocycles,which frequently occurs in naturally and synthetically bioactive products a
吡咯并吡咯二酮(DPP)类化合物是一类强荧光的生色团,在一定的激发波长照射下可以发射出明亮的红色荧光.由于其分子结构小、易修饰、荧光量子效率高、发光性能优异、光、热、
School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou,510640 The application of allylic alcohols,which are abundant in nat
Homogeneous Pd-mediated catalysts have been extensively applied in petrochemical industry,fine chemistry,biological catalysis and other fields based on their go