Graphene oxide as an anti-shrinkage additive for the preparation of resorcinol-formaldehyde composit

来源 :第十一届全国新型炭材料学术研讨会 | 被引量 : 0次 | 上传用户:shanian
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  In order to strengthen the nanostructure and suppress the collapse of nanopores of resorcinol-formaldehyde (RF) aero-gels,graphene oxide (GO) was incorporated into RF matrix to obtain GO/RF composite aerogels by sol-gel polymerization.The influence of GO content on the structure and physical properties of RF aerogels were investigated.The morphologies of composite aerogels were characterized by scanning electron microscopy,indicating good dispersion of graphene oxide in the RF matrix.In ad-dition,GO could obviously reduce both the drying shrinkage and density of aerogels.It was found that,as the content of GO in-creased from 0 to 2 wt% in the composite aerogels,the linear shrinkage decreased progressively from 28.3% t0 2.0 %,and simul-taneously,the density decreased from 506 t0 195 kg · m-3,implying that GO is a suitable additive for inhibiting the volume shrink-age of aerogels in drying.
其他文献
A novel nitrogen-containing carbon has been prepared by carbonization of polyaniline which is synthesized by in situ polymerization.Lithium storage performances have been investigated by galvanostatic
本文采用聚乙烯醇与活性炭复合,制备活性炭/有机多孔材料,继而经过预氧化及炭化,得到泡沫状多孔炭材料.将其与硫进行复合,作为Li-S电池正极材料.研究表明其具有良好的电化学性能,在100 mA/g的电流密度下,首次放电比容量为1280 mAh/g.同时该电极材料具有良好的倍率性能,循环稳定性和较高的充放电性能.
Green needle coke (GNC) was oxidized by mixing acid HNO3/H2SO4.The resulted oxidized material was named as intermediates which can be easily separated into two parts,water dispersible and water non-di
会议
过在酚醛树脂/聚乙烯醇纺丝原液中加入硅溶胶,经过静电纺丝、固化、炭化和洗涤制备了富含中孔的纳米炭纤维.加入硅溶胶后,纳米炭纤维的中孔含量从3%提高到83%.考察了所得中孔纳米炭纤维的电容性能.结果显示随着中孔含量的提高,炭纤维电极的倍率性能得到明显的改善,这主要归因于中孔的引入有效地提高了离子的传输速率.
本文采用水热法硼磷改性多孔炭,并对其电化学性能进行研究.通过X射线衍射、红外光谱以及氮气吸脱附来表征处理前后多孔炭的结构和性质;将样品用作电化学电容器电极,通过恒流充放电、循环伏安以及交流阻抗测试分析其电化学性能.研究结果表明,水热法硼磷改性使多孔炭的微观结构及组成发生了一定变化,比电容等电化学性能有明显的提高.渗硼剂为氧化硼,渗硼量为15 wt%时,比电容达108.10 F/g,相比原始样增长了
分别采用水热法和化学气相沉积法(CVD),制备两种同粒径(约360 nm)的碳微球(CMSs),并对CVD法制备的CMSs(CCMSs)用混酸溶液(浓硫酸:浓硝酸=3:1)进行酸化处理,在其表面引入含氧官能团,而水热法制备的CMSs(HC-MSs)不作处理;然后分别在N,N’-二环己基碳二亚胺的作用下,用1,6-己二胺修饰两种CMSs.通过场发射扫描电子显微镜和傅里叶红外光谱仪对产物的形貌和结构进
使用穿刺法将聚丙烯腈基炭纤维引入到泡沫石墨/环氧树脂复合材料中.当炭纤维的体积分数为1.O vol%时,复合材料沿纤维轴向的拉伸强度由3.4增高到10.3 MPa;演纤维的径向方向,抗弯强度由23.3增加到31.9 MPa.
A composite material composed of Graphene and Mn3O4 nanoparticles (GM composite) was prepared by microwave-assisted in-situ synthesis of Mn3O4 nanoparticles on the graphene nanosheets.SEM and TEM imag
会议
结合胶是未硫化的混炼胶中不能被其良溶剂溶解的那部分橡胶.用化学溶剂法制备结合胶具有药品用量小、实验过程操作简单,重现性好等优点.通过讨论橡胶加入量、炭黑用量、反应时间、静置时间等因素,确定了溶剂法制备结合胶的最佳工艺参数,并与混炼法制备的结合胶进行了性能对比.结果表明:在橡胶/甲苯溶液的浓度0.02g/ml,橡胶和炭黑的比例是2:1,反应时间为10小时,静置时间为72小时的工艺参数下,可以制得高质