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CNTs contents of 5wt%.,1Owt%,15wt%,20wt%PTMSDPA/CNTs hybrid composite membranes were prepared by a solution-casting method and the effect of structure and content of CNTs on gas separation and pervaporation performance of PTMSDPA/CNTs hybrid membrane were investigated.As the content of CNTs increased,the gas permeation coefficient of PTMSDPA/CNTs composite membranes mcreased,and got the maximum value at the content of 10wt%.The effect of inner diameter and length of CNT on gas permeation performance of PTMSDPA/CNTs membrane was deeper.