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The novel high-performance nanocomposites of polyaniline (PANI) and graphene oxide sheets (GOs) was synthesized via in situ polymerization in the presence of Hexadecyl trimethyl ammonium Bromide intercalated graphite oxide (CGO), basing on PANI and GOs as a matrix respectively.The result showed that ANI monomer was intercalated into the spacing of CGO, and the CGO was well exfoliated into nanosheets while polymerization.