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Two heavy-atom-free luminophores(SHB2t and SDB2t)with simple molecular structures that both display white-light emission with prompt fluorescence and room temperature phosphorescence(RTP)in the solid-state.The impressive RTP of the luminophores is produced by the spin-orbit coupling of the sulfonyl oxygen atoms in addition to a synergistic effect of the strong intermolecular hydrogen bonding and the moderate singlet-triplet energy gaps(ΔEST).