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The phase equilibria of the Cr-Hf-Ti ternary system have been firstly investigated by electron probe microanalyzer and X-ray diffraction on the equilibrated alloys.Three isothermal sections of the Cr-Hf-Ti ternary system at 1100 ℃,1200 ℃ and 1300 ℃ were determined,and this ternary system was thermodynamically optimized using the CALPHAD (CALculation of PHAse Diagrams) method.