Investigation of process conditions for catalytic conversion of carbohydrates by epimerization using

来源 :The 14th International Conference on Microreactivity Technol | 被引量 : 0次 | 上传用户：chting0910

【摘要】

：

　　Epimerization reactions are important processes for nutrition industry,dealing with the generation of different types or carbohydrates based on simple molec

【作者】

：

Berta Spasova Christof Kuesters Bruno Stengel Juergen J.Brandner

【机构】

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KarlsruheInstituteofTechnology(KIT),InstituteforMicroProcessEngineering,CampusNorth,Hermann-von-Helm

【出处】

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The 14th International Conference on Microreactivity Technol

【发表日期】

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2016年9期

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　　Epimerization reactions are important processes for nutrition industry,dealing with the generation of different types or carbohydrates based on simple molecules.The first example of an epimerization in general,the C2-epimerization of aldoses using the molybdate-catalyzed reaction from D-glucose to D-mannose,was observed in 1972 by Bilik1.The mechanism of the Bilik reaction does not involve an ene-diol transition state in contrast to the Lorby de Bruyn-Alberda van Ekenstein epimerization from glucose or fructose,which proceeds through an ene-diol transition state2,3.

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