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Aryl amines are a key synthetic unit widely utilized in organic synthesis, coordination chemistry, materials science and pharmaceutical industry.Current routes to those compounds require either prefunctionalized starting materials or external oxidants, thus inevitably generating stoichiometric amounts of side wastes.We have developed direct amidation and amination reactions of arene carbon-hydrogen (C-H) bonds using sulfonyl and aryl azides as the source of the nitrogen group to release molecular nitrogen as the single by-product.