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Hydrogen radiation-induced segregation(RIS)in AL-6XN stainless steels,which are one of the candidate structure materials for supercritical water-cooled reactor,has been investigated by transmission electron microscopy(TEM)with energy-dispersive X-ray spectroscopy.Specimens were irradiated with 50 keV H+ions from 0.5 to 5 dpa at 290℃ and 380℃.Significant RIS in irradiated specimens was found,Cr was depleted while Ni,Si and P were enriched at grain boundaries and it varies with the temperature and irradiation dose.The effects of hydrogen and elevated temperature on the segregation evolution were studied and the possible mechanism were discussed in this paper.