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Metatitanic acid was synthesized by using industrial titanyl sulfate solution via controlling PH during hydrolyzing process.ICP analysis confirms that a little Fe, Mg and Ca deposited into precursor TiO2·H2O.Spinel Li4Ti5O12 was prepared by sintering amorphous mixture at 800℃ for 16 hours.The amorphous was activated by ball-milling at room temperature, using the as-prepared TiO2·H2O and Li2CO3 as raw materials.