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Titanium bearing materials for blast furnace(BF)are usually adopted to protect the hearth refractories and prolong the campaign in iron-making process.However,the increase of cost and deterioration of operation are produced in practice.To solve the above problems,a new kind of carbon block containing TiO2 has been prepared as artificial graphite aggregate,reactive alumina,metallic aluminum,silicon and titania powder are used as starting materials in coke bed at 1200 and 1400℃.