单晶到单晶转换调控Fe(Ⅱ)配合物的结构及自旋交叉行为

来源 :中国化学会第十届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：kmyzkmyzkmyz

【摘要】

：

Fe(Ⅱ)自旋交叉配合物在温度、压力、光照等外在条件的影响下实现高低自旋的可逆转变,同时伴随着颜色、介电常数、电阻等物理化学性质的变化,因此在分子开关,高密度信息存储、显色器件等方面具有潜在的应用[1,2]。本文采用4-氨基-1,2,4-三氮唑配体与Fe(Ⅱ)在水热条件下合成了一例线性三核配合物[Fe3(NH2-trz)6(SCN)5(H2O)](SCN)·4H2O(1)。

【作者】

：

陈文斌董文

【机构】

：

广州大学化学化工学院,广州 510006

【出处】

：

中国化学会第十届全国无机化学学术会议

【发表日期】

：

2019年3期

【关键词】

：

单晶到单晶转换 Fe(Ⅱ)配合物自旋交叉

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

其他文献

Metal-Organic Frameworks from Multidentate Carboxylate Ligands with the Additional Function Groups:N

These two decades have witnessed the rapid development of metal-organic frameworks(MOFs)due to their fantastic structures and various potential applications,such as strategic gases storage and separat

会议

MOFssynthesisapplication

动态配位空间的构筑与调控

配位空间是多孔聚合物、金属-有机框架、金属-有机多面体等配合物结构和功能实现的重要基础。在不同外界诱导与刺激下(如光、热、气氛等)，配位空间可能发生动态结构转换与性能变化。这种动态效应使其在诸多方面如吸附分离、发光、催化、检测与识别等具有应用前景。

会议

配位空间动态行为设计调控

Photoinduced energy-and electron-transfer from a photoactive metal-organic cage to bound guests

In recent years,metal-organic cages(MOCs) constructed by coordination-driven self-assembly have been gradually developed,because of their well-defined hydrophobic cavities and the easy-modified organi

会议

Metal-Organic CagesSupramolecular behaviorPhotoinduced energy-transferPhotoin

Preparation and light-induced carbon monoxide delivery properties of Ru-CORM@hydrogel hybrid

Many studies have recently shown that low and safe dose of CO has been linked to display various physiological effects,such as anti-inflammatory,anti-apoptotic,anti-proliferative and vasodilation [1].

会议

Ru carbonyl complexCO releaseCS-PVApH responsive

Tuning the net topology of ternary Ag(Ⅰ)-1,2,4,5-tetra(4-pyridyl) benzene-carboxylate Framework:Stru

The dye molecule 1,2,4,5-tetra(4-pyridyl)benzene(bztpy),a tetradentate ligand,can be an excellent candidate to construct coordination polymers with photoluminescent properties.1 Here,three novel compl

会议

Crystal engineeringPhotoluminescentCoordination PolymerTetrapyridyl LigandAg

Multiphoton absorption materials:from design toward bioimaging and therapy

Multiphoton imaging is an effective strategy due to its excitation wavelength can be selected in near-infrared(NIR) optical tissue windows as well as its high spatial resolution.Recently,we have synth

会议

Multiphoton absorptionBioimagingPhotodynamic therapy

Constructing moisture-stable hybrid perovskite-type semiconductors based on hydrogen-bond-free strat

Hybrid perovskites-type light absorbers,notably based on methylammonium or formamidinium,have promising application in optoelectronics; however they are notorious for their characteristic low moisture

会议

PerovskiteLead iodineInorganic-organic hybridsPhotoconductionCrystal structu

混合配体策略调控钍基MOF增强光催化氧化

MOF的精准调节进而实现可控制备对于材料的结构和功能意义非凡.基于混合配体策略将卟啉衍生物、线性羧酸配体与六核钍簇结合构筑成新型的卟啉钍基有机框架材料Th-IHEP-5.由于联吡啶配体的引入,光活性卟啉基团的光敏效果进一步增强,Th-IHEP-5对CEES的光催化氧化的效果得到提升.

会议

混合配体MOF卟啉锕系金属Th光催化

Luminescent Edge-interlocked Prismatic Heteroleptic Metallocages Assembled Through a Ligand Replacem

For the great contributions in the research of molecular machines,Jean-Pierre Sauvage,Sir J.Fraser Stoddart and Bernard L.Feringa awarded the Nobel Prize in Chemistry 2016 jointly.1 Interlocked 3-D ca

会议

Interlocked structurecage compoundsluminescencemetallophilicity

蓝光铂(Ⅱ)配合物的激发态性质调控及应用

发光铂(Ⅱ)配合物具有丰富的光物理和光化学性质，因此在OLED、光催化、发光探针和细胞成像等领域有广泛的应用(图1)[1]。过渡金属配合物的三重态激发态性质如发光量子产率、激发态寿命和能量，决定了它们在不同应用领域的性能。因此，设计新型配体是开发新型激发态配合物材料的关键。

会议

铂(Ⅱ)配合物蓝光四齿配体OLED光催化

单晶到单晶转换调控Fe(Ⅱ)配合物的结构及自旋交叉行为

其他学术论文