Reactions of silane with cerium atoms:triply hydrogen-bridged Si(μ-H)3CeH and inserted H3SiCeH

• 作 者: PeipeiShi;BingXu;
• 机 构: Shanghai Key Lab of Chemical Assessment and Sustainability,Department of Chemistry,Tongji University
• 出 处: 中国化学会第30届学术年会
• 发表日期: 2016年期

　　Reactions of laser-ablated cerium atoms with silane in solid argon and krypton matrices havebeen investigated by matrix isolation FTIR and theoretical calculations.It is found that the ground state ceriumatoms can reactwith SiH4to form the Si(μ-H)3CeH and H3SiCeH spontaneously.