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Lithium ion batteries (LIBs) have become one of the most promising energy storage technologies for its many kinds of applications, such as electric vehicles (EVs), hybrid, hybrid electric vehicles (HEVs), medical engineering, and military areas.The performance of the lithium ion batteries could be connected with the materials categories and preparation processes which both lead to fabricating different nanostructured materials such as nanofibers, nanowires nanospheres and nanotubes.In this paper, we choose commercial vanadium oxides (V2O5), which are a typical intercalation compound with layered structure and can undergo multiple Li-insertion/extraction reactions, and benzyl alcohol and Isopropanol as the raw materials to form low-cost inorganic vanadium sol solution followed the propriate addition of poly(vinypyrrolidone)(PVP) as electrospinning vanadium precursor.Thus, we can prepare the one-dimensional (1D) V2O5 nanotubes(VNTs) ,which mainly containing V2O5 sol and PVP ,followed by varying the temperatures of sintering.The PVP contents in the PVP solution are devided into 10%,13%,16% and 20%.Cristal structure and the morphology of electrospun VNTs are analyzed by using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD).The electrospun VNTs ~100-400nm in dimeter,2-10μm long with various degrees of porous interconnected fibrous morphology which could be seen by SEM and TEM images.And the degrees of the fracture of the porous nanotubes are various with different temperatures.