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Hydrogel beads were prepared by free-radical polymerization of acrylate having poly(ethylene glycol) (PEG) as the side chain, and applied to adsorb precious metal ions such as Au, Pd and Pt.from acidic solutions prepared with hydrochloric acid.The gel beads had the greatest adsorption amount for Au, which is followed by Pt and Pd.Adsorption amount for Pt was similar to that for Pd.Adsorption equilibrium for the three metals were expressed with Freundlich-type equation.Experimental results of metal ion adsorption from multi-component mixture of Au, Pd and Pt suggested that Au was selectively adsorbed on the gel and the uptake of both Pd and Pt was suppressed.