Carbocyclization of 3-(indolin-1-yl)-3-oxopropanenitriles with Alkynes and Alkenes by Rhodium-Cataly

来源 :第十九届全国金属有机化学学术讨论会 | 被引量 : 0次 | 上传用户：fendoudeying

【摘要】

：

Rh(Ⅲ)-catalyzed carbocyclization reactions of 3-(indolin-1-yl)-3-oxopropanenitriles with alkynes and alkenes to form 1,7-fused indolines through C-H activation has been developed.

【作者】

：

周涛王佰全

【出处】

：

第十九届全国金属有机化学学术讨论会

【发表日期】

：

2016年7期

下载到本地 , 更方便阅读

下载此文赞助VIP

声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架

论文部分内容阅读

Rh(Ⅲ)-catalyzed carbocyclization reactions of 3-(indolin-1-yl)-3-oxopropanenitriles with alkynes and alkenes to form 1,7-fused indolines through C-H activation has been developed.

其他文献

Assembly of SnO2/α-Fe2O3 Nanoheterojunctions for Highly Efficient Photocatalytic Activation of Molec

Driven by the highly integrated impetuses of hydrolyzation,Ostwald ripening and structure-modification,nanostructured SnO2/α-Fe2O3 nanoheterojunctions with the morphologies of cone and hyacinthus orie

会议

NanoheterojunctionsApparent Quantum EfficienciesPhotocurrentLight absorption

C60(OH)n/CoP-codecorated CoP nanosheet as a robust and stable electrocatalyst for hydrogen evolution

High-activity electrocatalysts play a crucial role in energy conversion through splitting water to produce hydrogen.Here we fabricate a C60(OH)n/CoP-codecorated CoP Nanosheet which acts as an electroc

会议

electrocatalystnanoparticleoverpotentialhydrogen

Highly Enantioselective Michael Addition of 2-Acetyl Azaarenes to β-CF3-β-disubstituted Nitroalkenes

Cobalt-catalyzed asymmetric transformations have aroused continuous ever-growing interest during the last two decades due to its low cost and toxicity as well as excellent tolerance to various functio

会议

Fullerene-derived Three Dimensional Hierarchical Porous Microsheets for High-Performance Supercapaci

Fullerenes as one of the most interesting allotrope of carbon have been underdeveloped in energy storage because a high temperature(up to 2000 ℃)or the addition of templates or activators are always n

会议

fullerenesheat treatmentporositystabilitysupercapacitors

含(苯并咪唑)PCN钳形钯(Ⅱ)化合物的合成与催化性能

三齿配位的钳形钯化合物不仅结构容易修饰,而且已被证明是催化多种类型反应的有效催化剂.1 在以前的工作中,我们课题组发展了一种"一锅煮"的膦化/金属化反应,即由含氮给体的间苯酚类或苯胺类化合物先与适当的氯化膦反应、再与二价钯盐或镍盐原位进行金属化反应,成功地制得了多种类型的非手性和手性的PCN 钳形钯或镍化合物.该方法毋须分离不稳定的含膦配体、而且利用较廉价的简单Pd/Ni(Ⅱ)盐即可实现相关配体中

会议

Asymmetric C-H Insertion Reactions of1,4-Cyclohexadienewith3-Diazooxindoles Catalyzed by Bis(imidazo

Transition metal-catalyzed enantioselectiveinsertion of carbenefragments,generated from diazo reagents,into C-H bondprovides a promising,atom-economicalmethod for the formation of C-C bonds.

会议

Copper-Catalyzed Cyclization of 1,6-Enynes for the Synthesis of 2,4-Disubstituted α-Naphthol Derivat

The development of aromatic compounds and new methods for their construction has been of great interest,due to the fact that such moieties are present in various drugs and in devices used in the field

会议

C-H Bond Functionalization of Azoxybenzenes--ortho-Acylation,halogenation,Acetoxylation and Alkoxyla

Azoxy compounds,which have been widely applied in dyes,polymer inhibitors,and stabilizers,are key materials in electronic devices with wonderful liquid crystalline properties.

会议

Cooperative Interplay between a PNN-Ru(Ⅱ)Complex and NaBH4 in the Efficient Base-free Catalytic Hydr

In fact,we have developed a new NNP-tridentate ruthenium complex as highly efficient catalyst in the coupling cyclizations of γ-aminoalcohols with secondary alcohols.

会议

A Mild and Effecient Synthesis of N-Vinyl Tertiary Enamides via Ring-Opening Reaction of 2-Oxazoline

The stable enamide structure has been found to present in numerous natural products and active drugs.Enamides have been extensively used as versatile building blocks in various organic transformations

会议

Carbocyclization of 3-(indolin-1-yl)-3-oxopropanenitriles with Alkynes and Alkenes by Rhodium-Cataly

其他学术论文