含(苯并咪唑)PCN钳形钯(Ⅱ)化合物的合成与催化性能

来源 :第十九届全国金属有机化学学术讨论会 | 被引量 : 0次 | 上传用户：bluedogdog

【摘要】

：

三齿配位的钳形钯化合物不仅结构容易修饰,而且已被证明是催化多种类型反应的有效催化剂.1 在以前的工作中,我们课题组发展了一种"一锅煮"的膦化/金属化反应,即由含氮给体的间苯酚类或苯胺类化合物先与适当的氯化膦反应、再与二价钯盐或镍盐原位进行金属化反应,成功地制得了多种类型的非手性和手性的PCN 钳形钯或镍化合物.该方法毋须分离不稳定的含膦配体、而且利用较廉价的简单Pd/Ni(Ⅱ)盐即可实现相关配体中

【作者】

：

卢贝贝龚军芳宋毛平

【机构】

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郑州大学化学与分子工程学院,河南省化学生物与有机化学重点实验室,郑州450001

【出处】

：

第十九届全国金属有机化学学术讨论会

【发表日期】

：

2016年7期

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含(苯并咪唑)PCN钳形钯(Ⅱ)化合物的合成与催化性能

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