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Highly concentrated dye wastewater is often drained into environmental water during production and use，most of which is harmful to human health. Recently，we sought a new way to immobilize major component of dye wastewater in barite by co-precipitatio-n method，leading to cost-effective sorbents applicable to organic wastewater treat-ment. For instance，a barite-based sorbent was successfully yielded by immobilizati-on of weak acidic pink red B（APRB) from the dye wastewater. The experimental resul-ts showed that the sorbent has a very high adsorption capacity in removal of some c-ationic dyes，such as ethyl violet（EV)，cationic brilliant red 5GN（CBR)，methylen-e blue(MB) and Basic pink red B（BPR)，and four kinds of POPs（Fig. 1)，which attri-buted to high negative charge and lipophilic structure features of APRB.The adsorpt-ion of cationic dyes corresponded to the Langmuir isotherm modeland involved chargeattraction，and that of POPS corresponded to the octanol-waterpartition law and involved hydrophobic stacking. In addition，the hybrid sorbent wasregenerated from slud-ge over five cycles by acidification with adsorption capacityappreciably changed. T-his work has developed a simple，eco-friendly and practicalapproach for preparation of wastewater sorption material. Further studies are currentlyunder way.