论文部分内容阅读
研究了一系列金属萘酞菁配合物在光激发下产生单线态氧1O2的能力,结果表明,它们产生.能力的顺序为:ZnNc>NiNc>CoNc,ZnNc(OC4H9)8>ClMnNc(OC4H9)8>FeNc(OC4H9)8>NiNc(OC4H9)8>CuNc(OC4H9)8>CoNc(OC4H9)8;ZnNcS4>ZnNcBr4>ZnNc>ZnNc(OC4H9).着重讨论了中心金属离子、环取代基因以及浓度对金属萘酞菁配合物产生1O2能力的影响。
The ability of a series of metal naphthalocyanine complexes to generate singlet oxygen 1O2 under photoexcitation was studied and the results show that they are produced. (OC4H9) 8> FeNc (OC4H9) 8> NiNc (OC4H9) 8> CuNc (OC4H9) 8> CoNc (OC4H9) 8; ZnNcS4> ZnNcBr4 > ZnNc> ZnNc (OC4H9). The effects of central metal ions, ring-substituted genes and their concentration on the ability of metal naphthalocyanine complexes to produce 1O2 were emphatically discussed.