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Cd(NO3)·24H2O与配体4′,5′-二氮-9′-(4,5-二(硫乙基)-1,3-二硫杂环戊烯-2-叶立德)-芴(L)在甲醇和二氯甲烷的混合溶剂中生成配合物Cd(NO3)2(L)2。晶体的空间群是Pbcn(#60),晶体学参数分别是a=1.5787(2)nm,b=0.98796(11)nm,c=2.7195(3)nm。V=4.2416(8)nm3,Z=4。2个硝酸根离子各提供1个氧原子,2个配体L各提供2个氮原子,形成了镉的6配位结构。晶体结构显示分子通过平面之间的π-π相互作用沿b轴形成柱状结构,这些柱通过中心原子镉!的配位连接形成二维层状结构,再通过2个硫乙基上的短距离S…S接触进一步形成了三维结构。对其1HNMR、UV-Vis和荧光光谱进行了研究。
Cd (NO3) · 24H2O and the ligand 4 ’, 5’-diazepin-9’ - (4,5-bis (thioethyl) -1,3-dithiol-2-ylidene) (L) generates the complex Cd (NO3) 2 (L) 2 in a mixed solvent of methanol and dichloromethane. The crystal space group is Pbcn (# 60). The crystallographic parameters are a = 1.5787 (2) nm, b = 0.98796 (11) nm and c = 2.7195 (3) nm. V = 4.2416 (8) nm3, Z = 4.2 nitrate ions each provide one oxygen atom, two ligands L each provide two nitrogen atoms, forming a 6 coordination structure of cadmium. The crystal structure shows that the molecules form a columnar structure along the b-axis through the π-π interaction between the planes. These columns form a two-dimensional layered structure through the coordinate connection of the central atom Cd 2+ and then through a short distance S ... S contact further formed a three-dimensional structure. Its 1HNMR, UV-Vis and fluorescence spectra were studied.