论文部分内容阅读
在晶体场理论基础上,推导出了3d9离子在压缩四角对称晶场中2B1g态混合进基态2A1g的EPRg因子的三阶微扰公式.用该公式研究了晶体3Cu(IO3)2.2H2O中Cu2+离子两种占位的EPRg因子,并分别计算了它们的电子吸收能级,理论研究合理地解释了实验结果.
Based on the theory of crystal field, the third-order perturbation formula of EPRg factor of 2B1g mixed with 2A1g in the squeezed tetragonal symmetry crystal field is deduced. The Cu2 + ion in 3Cu (IO3) 2.2H2O EPRg factors of two kinds of placeholders, and calculate their electron absorption levels respectively. The theoretical research reasonably explained the experimental results.