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The title complex, formulated as {[Cd(pda)(phen)]?3H2O}n 1 (pda = 1,4-pheny- lenediacetate, phen = 1,10?-phenanthroline), has been hydrothermally synthesized and determim- ned by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) ?, ?α = 68.503(1), ?β = 86.371(1), ?γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) ?3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.
The title complex, formulated as {[Cd (pda) (phen)] 3H2O} n1 (pda = 1,4-pheny lenediacetate, phen = 1,10- phenanthroline), has been hydrothermally synthesized and determim- ned by X-ray crystallography. Crystallographic data: triclinic space group P1 a = 10.375 (7) b = 10.435 (1) c = 12.040 (1) Γ = 66.231 (1) °, Mr = 538.82, V = 1104.5 (8)? 3, Z = 2, Dc = 1.620 g / cm3, μ = 1.035 mm-1, the final R = 0.0380 and wR = 0.0985 (w = 1 / [σ2 (Fo2) + (0.0559P) 2 + 1.5319P] where P = (Fo2 + 2Fc2) / 3) based on 3444 observed reflections with I> 2σ (I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it shows intense green luminescence with the maximum at around 516 nm.