Synthesis, Structure and Characterization of [Cu（2,2＇-bpy）2][{Cu（2,2＇-bpy）2}2W12O40（H2）]·4H2O

• 作 者: HE Li-Wen LIN Bi-Zhou LIU Xue-
• 机 构: CollegeofMaterialsScienceandEngineering
• 出 处: 结构化学
• 发表日期: 2007年12期
• 关键词: 多缩含氧酸 铜 混合物 氢键 化学分析 晶体结构 polyoxotungstate copper compound hydrothermal synthes
• 基金项目: This work was supported by the Natural Science Foundation of Fujian Province （No. E0420001） and NCETFJ.

An organic-inorganic compound [Cu(2,2′-bpy)2][{Cu(2,2′-bpy)2}2W12O40(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4·2H2O, CuCl2·2H2O, 2,2′-bipyridine (2,2′-bpy) and H2O at 160 ℃ for 4 days. The compound cryst