2-甲基-3-丁烯-2-醇+直链一元醇二元体系的过量摩尔体积和表观摩尔体积298.15 K)

• 作 者: 刘迪霞 李浩然 邓东顺 韩世钧
• 机 构: Department of Chemistry
• 出 处: 中国化学工程学报
• 发表日期: 2004年期
• 关键词: excess molar volume binary mixture 2-methyl-3-buten-2-ol 1-alcohol apparent mola
• 基金项目: 国家自然科学基金

Excess molar volumes (VEm) of binary mixtures of 2-methyl-3-buten-2-ol [CH3C(OH)(CH3)CHCH2]with four 1-alcohols: methanol, ethanol, 1-propanol and 1-butanol at 298.15 K and atmospheric pressure are derived from density measurements with a vibrating-tube densimeter. All the excess volumes are negative in the systems over the entire composition range. The results are correlated with the Redlich-Kister equation. The effects of chain length of 1-alcohols on VmE are discussed. The apparent molar volumes of 2-methyl-3-buten-2-ol and 1-alcohols are calculated respectively.