Synthesis,Crystal Structure and Properties of a Coordination Compound:Ni(C_6H_(12)N_4)_2SO_4·4H_2O

• 作 者: 高晟民 许智煌 叶李旺 苏根博 庄欣欣
• 机 构: Key Laboratory of Optoelectronic Materials Chemistry and Physics,Fujian Institute of Research on the
• 出 处: 结构化学
• 发表日期: 2015年11期
• 关键词: octahedral gravimetric stretching triclinic belongs nickel dehydration ultraviol

A new coordination compound,Ni(C6H12N4)2SO4·4H2O(NSH-HMTA)(HMTA,hexamethylenetetramine,C6H12N4),has been synthesized and its single crystals were obtained.NSH-HMTA belongs to the triclinic system,space group P1 with a=9.2534(6),b=13.3131(2),c=16.0373(2) ?,α=65.981(6),β=89.792(3),γ=89.677(4)°,Mr=880.2,Z=2,V=1804.6(3) ?3,μ=1.254 mm-1,F(000)=932,R=0.0555(I > 2σ(I)) and w R=0.1908 for 19343 observed reflections.HMTA substitutes for water molecules are located at the para-positions,forming a stretching octahedral nickel ion unit.Thermo-gravimetric analysis shows that the dehydration temperature of NSH-HMTA is about 92 ℃.The characteristic UV peaks are approximately 10 nm red-shifted by the absorption of octahedral HMTA complex ion units.

A new coordination compound, Ni (C6H12N4) 2SO4.4H2O (NSH-HMTA) (HMTA, hexamethylenetetramine, C6H12N4), has been synthesized and its single crystals were obtained.NSH- HMTA belongs to the triclinic system, space group P1 with a = Α = 65.981 (6), β = 89.792 (3), γ = 89.677 (4) °, Mr = 880.2, Z = 2, V = 1804.6 (3)? 3, μ = 1.254 mm-1, F (000) = 932, R = 0.0555 (I> 2σ (I)) and w R = 0.1908 for 19343 observed reflections.HMTA substitutes for water molecules are located at the para-positions, forming a stretching octahedral nickel ion unit. Thermo-gravimetric analysis shows that the dehydration temperature of NSH-HMTA is about 92 ° C. The characteristic UV peaks are approximately 10 nm red-shifted by the absorption of octahedral HMTA complex ion units.